Starch Films Reinforced with Pistachio Shell Particles: A Sustainable Biocomposite.

This study investigates the development of corn starch-based biocomposites reinforced with pistachio shell powder, focusing on improving their mechanical and thermal performance. Composite films were prepared by solution casting with pistachio shell contents ranging from 2 wt% to 8 wt% by weight. The materials were characterized using Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), X-ray diffraction (XRD), and tensile testing. The incorporation of pistachio shell particles led to a progressive improvement in tensile strength and elastic modulus, with the highest values observed in the formulation with 8% reinforcement (SP08). The TGA results indicated a shift in degradation temperatures for the sample with the highest percentage, reflecting a higher thermal stability that is attributed to the interactions between the starch, plasticizer, and cellulosic components of the pistachio shell. The FITR spectra shows very similar structures between starch and pistachio. An XRD analysis shows the alpha-type structure for starch and the cellulose type 1 structure for pistachio. Overall, the results suggest that pistachio shell powder can serve as an effective natural reinforcement, improving the functional properties of starch matrices and promoting the development of environmentally friendly materials derived from agro-industrial waste.