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一种用于检测环境样品中消炎镇痛药氟芬那酸的新型一次性竹基生物炭电化学传感器。

A Novel Disposable Bamboo Biochar-Based Electrochemical Sensor for Detecting the Nonsteroidal Anti-Inflammatory Drug Flufenamic Acid in Environmental Samples.

作者信息

Silva Francisco Walison Lima, Teixeira Luís Eduardo da Conceição, Bernardino Cassiano Augusto Rolim, Mahler Claudio Fernando, Borges Renata Coura, Santelli Ricardo Erthal, Cincotto Fernando Henrique

机构信息

Departamento de Química Analítica, Instituto de Química, Universidade Federal do Rio de Janeiro, Rio de Janeiro 21941-909, Brazil.

Departamento de Engenharia Civil, COPPE, Universidade Federal do Rio de Janeiro, Rio de Janeiro 21941-914, Brazil.

出版信息

ACS Omega. 2025 Aug 5;10(32):36724-36732. doi: 10.1021/acsomega.5c06160. eCollection 2025 Aug 19.

Abstract

This study presents an electrochemical platform for the detection of flufenamic acid using a bamboo biochar-modified screen-printed electrode (denoted as SPE/BCB). The proposed sensor exhibited high analytical performance, with a sensitivity of 2.30 μA/μmol L and an ultralow detection limit of 1.3 nmol L, across a broad linear range (0.05-13.32 μmol L). Compared with conventional electrodes such as glassy carbon, carbon paste, and modified pyrolytic graphite electrodes, the SPE/BCB sensor offers advantages in terms of cost-effectiveness, ease of fabrication, and disposability. The incorporation of bamboo biochar enhances the electrochemical performance while providing an environmentally friendly approach. Furthermore, the sensor demonstrates excellent selectivity, remaining unaffected by common organic interferents, making it suitable for environmental applications. Its ability to accurately quantify FFA in complex aqueous matrices, including river and tap water, highlights its potential as an effective tool for environmental monitoring.

摘要

本研究提出了一种使用竹生物炭修饰的丝网印刷电极(记为SPE/BCB)检测氟芬那酸的电化学平台。所提出的传感器具有高分析性能,在宽线性范围(0.05 - 13.32 μmol/L)内,灵敏度为2.30 μA/μmol/L,检测限低至1.3 nmol/L。与玻碳、碳糊和修饰热解石墨电极等传统电极相比,SPE/BCB传感器在成本效益、易于制造和可一次性使用方面具有优势。竹生物炭的加入增强了电化学性能,同时提供了一种环境友好的方法。此外,该传感器具有出色的选择性,不受常见有机干扰物的影响,适用于环境应用。它能够准确量化包括河水和自来水在内的复杂水基质中的FFA,突出了其作为环境监测有效工具的潜力。

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