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基于赤泥的人造轻集料的制备及物理性能

Preparation and Physical Properties of Red Mud Based Artificial Lightweight Aggregates.

作者信息

Han Rubin, Zhao Yunrui, Luo Hui, Leng Hongxiu, Wu Wenbo, Song Bukai, He Bao-Jie

机构信息

School of Civil and Ocean Engineering, Jiangsu Ocean University, Lianyungang 222005, China.

Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China.

出版信息

Materials (Basel). 2025 Aug 10;18(16):3741. doi: 10.3390/ma18163741.

Abstract

Highly alkaline and highly toxic red mud and other bulk industrial solid wastes become severely accumulated, posing huge risks such as soil degradation and environmental pollution. It is urgent to develop a long-term and stable resource disposal method. In the present research, artificial lightweight aggregates were fabricated utilizing industrial solid residues including red mud, phosphate tailing powder, and fly ash as raw materials. The physical characteristics, microstructure, heavy metal leaching attributes, and freeze-thaw resistance under different mixed water and curing conditions were studied. The results showed that, under the optimal curing condition (steam curing temperature of 80 °C and curing time of 10 h), lightweight aggregates exhibited the best comprehensive performance, with favorable trends in bulk density, apparent density, softening coefficient, and 1 h water absorption. In addition, the impact of extending the curing time on the further enhancement of the cylinder crush strength is limited. The microscopic morphology study showed that the hydration products in lightweight aggregates are primarily N-A-S-H and C-(A)-S-H, forming a strong colloidal structure and evenly dispersed on the particle surface, thereby improving its strength. Moreover, the heavy metal leachates (Cr, Pb, As, Cu, and Ni) from the lightweight aggregates met the environmental discharge criteria for non-hazardous substances.

摘要

高碱性且剧毒的赤泥等大宗工业固体废物堆积严重,带来土壤退化和环境污染等巨大风险。亟待研发一种长期稳定的资源处置方法。在本研究中,利用包括赤泥、磷尾矿粉和粉煤灰在内的工业固体废弃物作为原料制备人造轻集料。研究了不同拌合水和养护条件下轻集料的物理特性、微观结构、重金属浸出特性及抗冻融性。结果表明,在最佳养护条件(蒸汽养护温度80℃、养护时间10 h)下,轻集料表现出最佳综合性能,在堆积密度、表观密度、软化系数和1 h吸水率方面呈现良好趋势。此外,延长养护时间对进一步提高筒压强度的影响有限。微观形貌研究表明,轻集料中的水化产物主要为N-A-S-H和C-(A)-S-H,形成强胶体结构并均匀分散在颗粒表面,从而提高其强度。而且,轻集料中的重金属浸出液(Cr、Pb、As、Cu和Ni)符合非有害物质的环境排放标准。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/54b1/12387215/8be3908d4bd9/materials-18-03741-g001.jpg

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