Yoo Hyunjae, Lee Yun Hyeok, Lee Min-Gyu, Sun Jeong-Yun
Department of Materials Science and Engineering, Seoul National University, Seoul 08826, Republic of Korea.
Research Institute of Advanced Materials (RIAM), Seoul National University, Seoul 08826, Republic of Korea.
Chem Rev. 2025 Sep 24;125(18):8956-9011. doi: 10.1021/acs.chemrev.5c00245. Epub 2025 Sep 2.
Ionic circuits have emerged as a promising candidate to bridge the gap between biological and artificial systems by applying the mechanically compliant and adaptive nature of gels as ionic conductors. Gel-based ionic circuits exploit the intrinsic characteristics of ions, such as their mass, diversity, and local accumulation, to achieve selectivity, hysteresis, and chemical-electric signal transduction. Their dynamic and nonlinear behaviors not only emulate traditional solid-state electronic systems but also exhibit unique functionalities and operating mechanisms extending beyond established electronic paradigms. In this review, we categorize gel-based ionic circuits into four major functional classes: passive circuit elements, active circuit elements, power sources, and noncircuit elements. We comprehensively discuss the fundamental operating principles, materials strategies, and current challenges, eventually highlighting opportunities for future advancement in ionic devices.