Liu Zhoufei, Jin Peng, Lei Min, Wang Chengmeng, Zhuang Pengfei, Tan Peng, Jiang Jian-Hua, Marchesoni Fabio, Huang Jiping
Department of Physics, State Key Laboratory of Surface Physics, Fudan University, Shanghai 200438, P. R. China.
Key Laboratory of Micro and Nano Photonic Structures (Ministry of Education), Fudan University, Shanghai 200438, P. R. China.
Chem Rev. 2025 Sep 24;125(18):8655-8730. doi: 10.1021/acs.chemrev.4c00912. Epub 2025 Sep 8.
Diffusion is a fundamental process in the transfer of mass and energy. Diffusion metamaterials, a class of engineered materials with distinctive properties, enable precise control and manipulation of diffusion processes. Meanwhile, topology, a branch of mathematics, has attracted growing interest within the condensed matter physics community. Recently, the integration of diffusion metamaterials and topology has established a groundbreaking framework for understanding and controlling mass and energy transport processes. This review examines the rapidly emerging field of topological diffusion metamaterials, emphasizing how topological principles enhance robustness and precision in diffusion-driven systems, including thermal, particle, and plasma transport. The foundational theories of this field integrate basic topological theories from topological physics with the core theories of diffusion metamaterials, encompassing transformation theory and its various extensions. Additional related topics, beyond metamaterials, are also discussed. These advancements may have significant applications in various disciplines, including chemistry, enabling unprecedented levels of control in areas such as microfluidic heat management, targeted drug delivery, plasma etching, and beyond.
扩散是质量和能量传递中的一个基本过程。扩散超材料是一类具有独特性质的工程材料,能够对扩散过程进行精确控制和操纵。与此同时,拓扑学作为数学的一个分支,在凝聚态物理领域引起了越来越多的关注。最近,扩散超材料与拓扑学的结合为理解和控制质量与能量传输过程建立了一个开创性的框架。本综述探讨了拓扑扩散超材料这一迅速兴起的领域,强调拓扑原理如何增强扩散驱动系统(包括热传输、粒子传输和等离子体传输)中的鲁棒性和精确性。该领域的基础理论将拓扑物理的基本拓扑理论与扩散超材料的核心理论相结合,包括变换理论及其各种扩展。还讨论了超材料之外的其他相关主题。这些进展可能在包括化学在内的各个学科中具有重要应用,能够在微流体热管理、靶向药物递送、等离子体蚀刻等领域实现前所未有的控制水平。