Gueye Ibrahima, Yasui Akira, Takagi Yasumasa, Ogura Atsushi, Sakata Osami, Nagata Takahiro
National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan.
Japan Synchrotron Radiation Research Institute, Sayo, Hyogo 679-5198, Japan.
ACS Appl Mater Interfaces. 2025 Sep 24;17(38):54241-54253. doi: 10.1021/acsami.5c13299. Epub 2025 Sep 9.
In this study, we analyze InO thin-film transistors (InO-TFT) using synchrotron-based hard X-ray photoelectron spectroscopy (HAXPES) in conditions. A bottom-gate InO-TFT with a high- AlO gate dielectric, grown on thermally oxidized silicon (SiO/p-Si), was examined while operating at varying and . The results reveal that the In 3d core level binding energy varies along the horizontal channel length, driven by the potential gradient induced by . Furthermore, the polarity of under positive significantly affects the channel structure, and influences the vertical electrostatic potential in the buried gate dielectric and the gate electrode. Analysis suggests that the primary source of drain-source leakage current () arises from high intrinsic electron and defect/trap levels associated with oxygen vacancies (). Additionally, investigation beneath the Au/Ti drain and source electrodes under different bias voltages reveals substantial InO reduction, leading to significant indium metal (In) formation. Schematic models of carrier transport mechanisms are proposed to explain these findings.