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高Z光学活性分子中不对称正电子素形成的限制

Limits on asymmetric orthopositronium formation in high Z optically active molecules.

作者信息

Van House J, Rich A, Zitzewitz P W

出版信息

Orig Life Evol Biosph. 1985;16(1):81-7. doi: 10.1007/BF01808051.

Abstract

The proposed connection between the parity violating handedness of beta particles in radioactive decay and the sign (L) of biological chirality (the Vester-Ulbricht [V-U] hypothesis) is experimentally tested. The theoretically predicted asymmetry in triplet positronium formation (Aps) is measured in several high Z optically active molecules using low energy positrons with a net helicity. We find Aps less than 3 X 10(-4) in selenocystine (Z = 34) and thyroxine (Z = 53), excluding part of the theoretically predicted range of 4 X 10(-3) greater than Aps greater than 2 X 10(-6) in these molecules. The connection between these limits and limits on asymmetric radiolysis (AR) is made, with a new limit of AR greater than 10(-9) being placed. This limit on AR, which is thirty times lower than a previous measurement in the amino acid leucine (Z = 6), is still not small enough to rule out the V-U hypothesis. rule out the V-U hypothesis.

摘要

对放射性衰变中β粒子的宇称破坏手征性与生物手征性符号(L)之间的假定联系(维斯特 - 乌尔布里希[V - U]假说)进行了实验检验。使用具有净螺旋度的低能正电子,在几种高Z值的旋光分子中测量了三重态正电子素形成过程中理论预测的不对称性(Aps)。我们发现在硒代胱氨酸(Z = 34)和甲状腺素(Z = 53)中Aps小于3×10⁻⁴,排除了这些分子中理论预测范围4×10⁻³>Aps>2×10⁻⁶的部分。建立了这些限制与不对称辐射分解(AR)限制之间的联系,并给出了AR>10⁻⁹的新限制。这个AR限制比之前在氨基酸亮氨酸(Z = 6)中的测量值低三十倍,但仍不足以排除V - U假说。排除V - U假说。

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