Liu Dan, Jiang ShaoYi, Li WeiTian, Yang Song, Liu XueChao, Sun JingXuan, Ding MinGao, Xue YunZhou, He ShaoLong, Li RongBing, Wang Ying, Gao Pan
Shanghai DianJi University, Shanghai 201306, China.
Shenzhen HiMachines Electronic Equipment Technology Co., LTD, Shenzhen 518110, China.
ACS Omega. 2025 Aug 11;10(35):40492-40500. doi: 10.1021/acsomega.5c05911. eCollection 2025 Sep 9.
Silicon carbide (SiC), a wide-band gap semiconductor, is essential for applications in electric vehicles, 5G communications, and aerospace due to its outstanding physical properties. However, their high production costs limit their widespread industrial applications. The growth of larger diameter and thicker crystals, particularly 8 in. crystals, offers the potential to reduce these costs. Therefore, large-diameter PVT crystal growth equipment with resistance heating has become a focal point of research in this field. In this paper, a novel double-flap resistance furnace design is proposed for the first time, and the thermal field is systematically studied by three-dimensional COMSOL Multiphysics modeling to optimize the growth of 8 in. 4H-SiC single crystals. It is found that the resistance heating system significantly outperforms the induction heating system by providing a lower radial temperature gradient necessary for large-diameter SiC crystals. Additionally, the influence of key parameters such as the crucible, the distance between the heater and the crucible, and the growth power on the thermal field distribution in the crucible was also systematically studied. The influence of the distance from the surface of the source material to the crystal surface and the distance from the center of the crystal to the edge on both the axial and radial temperature differences is also analyzed. Based on the simulation results, the crystal growth scheme was further optimized and an 8 in. SiC crystal with a thickness above 20 mm and resistivity uniformity was successfully obtained using the novel resistance furnace. This is of great significance for the growth of large-diameter SiC crystals.
碳化硅(SiC)作为一种宽带隙半导体,因其优异的物理性能,在电动汽车、5G通信和航空航天领域的应用中至关重要。然而,其高昂的生产成本限制了它们在工业上的广泛应用。生长更大直径和更厚的晶体,特别是8英寸的晶体,具有降低这些成本的潜力。因此,具有电阻加热功能的大直径物理气相传输(PVT)晶体生长设备已成为该领域的研究重点。本文首次提出了一种新颖的双瓣电阻炉设计,并通过三维COMSOL Multiphysics建模对热场进行了系统研究,以优化8英寸4H-SiC单晶的生长。研究发现,电阻加热系统通过为大直径SiC晶体提供较低的径向温度梯度,显著优于感应加热系统。此外,还系统研究了坩埚、加热器与坩埚之间的距离以及生长功率等关键参数对坩埚内热场分布的影响。还分析了源材料表面到晶体表面的距离以及晶体中心到边缘的距离对轴向和径向温差的影响。基于模拟结果,进一步优化了晶体生长方案,并使用新型电阻炉成功获得了厚度超过20mm且电阻率均匀的8英寸SiC晶体。这对于大直径SiC晶体的生长具有重要意义。