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通过物理气相传输法优化150毫米碳化硅晶体生长的热场

Optimization of thermal field of 150 mm SiC crystal growth by PVT method.

作者信息

Zhang Shengtao, Fan Guofeng, Li Tie, Zhao Lili

机构信息

Harbin Institute of Technology, School of Chemistry and Chemical Engineering Heilongjiang 150001 China

Soft-Impact China (Harbin), Ltd Heilongjiang 150028 China.

出版信息

RSC Adv. 2022 Jul 8;12(31):19936-19945. doi: 10.1039/d2ra02875a. eCollection 2022 Jul 6.

DOI:10.1039/d2ra02875a
PMID:35865196
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9264332/
Abstract

The excellent physical properties of SiC as an electronic material determine its important application prospects, especially in the new-energy industry, but the preparation of large-sized materials with high quality is not easy. Therefore, the physical fields in the growth process were modeled and studied with the help of the numerical simulation software Virtual Reactor, and its accuracy was verified by the agreement between morphology of the experimental crystal and the simulation. Additionally, the effects of thermal insulation adjustment of crystal growth thermal fields, application of seed crystals with different diameters, and shelter structure on the crystal growth process were also studied. By optimizing the crystal growth conditions, a nearly flat and slightly convex crystal growth interface was obtained successfully in our lab. Crystal quality was significantly improved, and a 6-inch SiC crystal with single polytype, high quality and low defects was successfully prepared.

摘要

碳化硅作为一种电子材料具有优异的物理性能,这决定了其重要的应用前景,尤其是在新能源产业中,但高质量大尺寸材料的制备并非易事。因此,借助数值模拟软件Virtual Reactor对生长过程中的物理场进行了建模和研究,并通过实验晶体形态与模拟结果的一致性验证了其准确性。此外,还研究了晶体生长热场的保温调节、不同直径籽晶的应用以及遮蔽结构对晶体生长过程的影响。通过优化晶体生长条件,在我们实验室成功获得了近乎平坦且略呈凸形的晶体生长界面。晶体质量显著提高,成功制备出了具有单一多型、高质量且低缺陷的6英寸碳化硅晶体。

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