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用于催化染料降解、可再生能源及储能应用的多功能过渡金属氧化物/氧化石墨烯纳米复合材料。

Multifunctional transition metal oxide/graphene oxide nanocomposites for catalytic dye degradation, renewable energy, and energy storage applications.

作者信息

Pasindu Viraj, Yapa Piumika, Dabare Sanduni, Munaweera Imalka

机构信息

Department of Chemistry, Faculty of Applied Sciences, University of Sri Jayewardenepura Nugegoda 10250 Sri Lanka

出版信息

RSC Adv. 2025 Sep 12;15(40):33162-33186. doi: 10.1039/d5ra04806k. eCollection 2025 Sep 11.

Abstract

The worsening global environmental and energy crises involving industrial water pollution, carbon emissions and clean, sustainable energy requirements call for innovative multifunctional materials. Transition metal oxide/graphene oxide (TMO/GO) nanocomposites represent an advanced material group through their ability to integrate redox properties of transition metal oxides and catalytic characteristics with graphene derivative characteristics, which include electrical conductivity, low surface area, and exceptional mechanical strength. While TMO/GO composites demonstrate promising multifunctional abilities in dye degradation, energy storage, and renewable energy applications, critical challenges remain unaddressed. First, scalable synthesis methods for defect-free graphene hybrids with uniform TMO nanoparticle distribution are underdeveloped, as current solvothermal or sol-gel approaches often yield inconsistent morphologies and require surfactants or toxic solvents. Second, the long-term stability of these composites under operational conditions remains poorly characterized, with limited studies on mechanical degradation or leaching of toxic metal ions. Third, while individual functionalities (photocatalysis, capacitance) are well-studied, synergistic optimization of dual/multifunctional performance is largely unexplored. This review gives a thorough examination of synthesis methods (sol-gel and hydrothermal) and metal doping protocols for surface functionalization and TMO/GO composite behavior related to their unique applications. This review gives a thorough examination of synthesis methods (sol-gel and hydrothermal) and metal doping protocols for surface functionalization and TMO/GO composite behavior related to their unique applications. The paper evaluates existing research gaps and sustainability factors by delivering an analytical assessment of the scalability as well as durability, and sustainable development applicability across next-generation clean water technologies and renewable energy conversion and energy storage systems.

摘要

日益严重的全球环境和能源危机,涉及工业水污染、碳排放以及对清洁、可持续能源的需求,这就需要创新的多功能材料。过渡金属氧化物/氧化石墨烯(TMO/GO)纳米复合材料是一类先进材料,它们能够将过渡金属氧化物的氧化还原特性和催化特性与石墨烯衍生物的特性(包括导电性、低表面积和出色的机械强度)整合在一起。虽然TMO/GO复合材料在染料降解、能量存储和可再生能源应用中展现出了有前景的多功能能力,但关键挑战仍未得到解决。首先,用于制备具有均匀TMO纳米颗粒分布的无缺陷石墨烯杂化物的可扩展合成方法尚不完善,因为目前的溶剂热法或溶胶-凝胶法往往会产生不一致的形态,并且需要表面活性剂或有毒溶剂。其次,这些复合材料在运行条件下的长期稳定性仍未得到充分表征,关于机械降解或有毒金属离子浸出的研究有限。第三,虽然对单个功能(光催化、电容)已有充分研究,但对双功能/多功能性能的协同优化在很大程度上尚未探索。本综述全面考察了合成方法(溶胶-凝胶法和水热法)以及用于表面功能化的金属掺杂方案,以及与TMO/GO复合材料独特应用相关的行为。本文通过对可扩展性、耐久性以及在下一代清洁水技术、可再生能源转换和储能系统中的可持续发展适用性进行分析评估,来评估现有的研究差距和可持续性因素。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/14af/12426755/43f9cadd0789/d5ra04806k-f1.jpg

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