涉及环庚三烯酮的环加成和官能团化反应。

Doraghi Fatemeh, Edareh Mohammad Hadi, Larijani Bagher, Mahdavi Mohammad

Endocrinology and Metabolism Research Center, Endocrinology and Metabolism Clinical Sciences Institute, Tehran University of Medical Sciences Tehran Iran

School of Chemistry, College of Science, University of Tehran Tehran Iran.

RSC Adv. 2025 Sep 19;15(41):34282-34299. doi: 10.1039/d5ra05481h. eCollection 2025 Sep 17.

Tropones are valuable moieties in the synthesis of natural products and bioactive molecules. Tropones have also emerged as fascinating synthetic partners for various (4 + 2)-, (4 + 6)-, (6 + 3)-, (6 + 4)-, (6 + 6)-, (8 + 2)-, and (8 + 3)-cycloaddition reactions as well as functionalization reactions. This review highlights various cycloaddition and functionalization reactions involving tropone building blocks reported since 2014.

卓酚酮在天然产物和生物活性分子的合成中是有价值的部分。卓酚酮也已成为各种（4 + 2）-、（4 + 6）-、（6 + 3）-、（6 + 4）-、（6 + 6）-、（8 + 2）-和（8 + 3）-环加成反应以及官能团化反应中引人入胜的合成伙伴。本综述重点介绍了自2014年以来报道的涉及卓酚酮结构单元的各种环加成和官能团化反应。