Wang Cunfei, Zhang Lihui, Liang Bing, Wang Junguang, Wu Pengfei
School of Mining Engineering, Liaoning Technical University, Fuxin, 123000, Liaoning, China.
Shenhua Shendong Coal Group Corporation Limited, 017209, Ordos, Inner Mongolia, China.
Sci Rep. 2025 Sep 26;15(1):33133. doi: 10.1038/s41598-025-18523-8.
Traditional concrete materials are expensive and ecologically detrimental, presenting significant challenges in balancing construction cost control with durability requirements for underground roads. To enable near-site, high-value utilization of bulk coal-based solid waste while optimizing coal mine roadway concrete performance, a fly ash-coal gangue concrete is developed in this study. In this material, natural crushed stone aggregates are substituted with coal gangue and cement is replaced with fly ash. Using coal gangue replacement rates (0%, 20%, 40%, 60%, 80%, 100%) and fly ash content (0%, 10%, 20%) as experimental variables, fresh concrete workability was assessed via slump tests; Strength characteristics and drying shrinkage behavior of hardened concrete were evaluated through compressive and flexural strength testing; Pore structure characteristics were analyzed using nuclear magnetic resonance (NMR); The optimization effect of triethanolamine dosages (0%, 0.01%, 0.03%, 0.05%) on drying shrinkage and mechanical properties was investigated in high-fly-ash-content concrete. The results demonstrate that concrete slump is significantly reduced by coal gangue content exceeding 40%, whereas workability is enhanced by appropriate fly ash addition; Concrete strength is diminished by elevated coal gangue content, necessitating a maximum dosage of 40%; Concrete compactness is improved and pore structure is refined by 10% fly ash content, while pore structure integrity is degraded by 20% fly ash; Drying shrinkage is increased by coal gangue but effectively mitigated by fly ash incorporation; Both drying shrinkage resistance and mechanical strength of fly ash-coal gangue concrete are substantially optimized by adding 0.03% triethanolamine.
传统混凝土材料价格昂贵且对生态环境有害,在平衡地下道路建设成本控制与耐久性要求方面面临重大挑战。为了在优化煤矿巷道混凝土性能的同时,实现大宗煤基固体废弃物的近场高价值利用,本研究开发了一种粉煤灰 - 煤矸石混凝土。在这种材料中,用煤矸石替代天然碎石骨料,并用粉煤灰替代水泥。以煤矸石替代率(0%、20%、40%、60%、80%、100%)和粉煤灰含量(0%、10%、20%)作为实验变量,通过坍落度试验评估新拌混凝土的工作性;通过抗压和抗折强度试验评估硬化混凝土的强度特性和干燥收缩行为;使用核磁共振(NMR)分析孔隙结构特征;研究了三乙醇胺用量(0%、0.01%、0.03%、0.05%)对高粉煤灰含量混凝土干燥收缩和力学性能的优化效果。结果表明,煤矸石含量超过40%会显著降低混凝土坍落度,而适当添加粉煤灰可提高工作性;煤矸石含量升高会降低混凝土强度,最大用量需控制在40%;10%的粉煤灰含量可提高混凝土密实度并细化孔隙结构,而20%的粉煤灰会降低孔隙结构完整性;煤矸石会增加干燥收缩,但掺入粉煤灰可有效减轻;添加0.03%的三乙醇胺可大幅优化粉煤灰 - 煤矸石混凝土的抗干燥收缩性能和力学强度。