Development of Xanthan Gum-Modified Coal-Fly-Ash-Based Cementitious Firefighting Materials with Improved High-Temperature Resistance for Coal Mines.

In this study, xanthan gum (XG)-modified coal-fly-ash-based cementitious materials were synthesized to realize the resource utilization of coal fly ash and to develop a low-carbon emission cementitious sealing material that can substitute cement-based sealing material to prevent coal fires. The optimal formulation for coal-fly-ash-based mining cementitious sealing material was developed using response surface methodology based on Box-Behnken Design. The optimized formulation was obtained with a coal fly ash-to-precursor ratio of 0.65, alkali-activator modulus of 1.4, and alkali-activator dosage of 7.5%. Under the optimal conditions, the initial and final setting time were 26 min and 31 min, respectively, fluidity was 245 mm, and the 7-day compressive strength approached 36.60 MPa, but there were still thermal shrinkage and cracking phenomena after heating. XG was then introduced to improve the thermal shrinkage and cracking of coal-fly-ash-based cementitious materials. Incorporating 1 wt.‱ XG was found to decrease the fluidity while maintaining the setting time and increasing the 1-day and 7-day compressive strength by 15.44% and 1.97%, respectively. The results demonstrated that the gels generated by XG cross-linking and coordinating with Al/Ca were interspersed in the original C(N)-A-S-H gel network, which not only made the 1 wt.‱ XG modified coal-fly-ash-based cementitious material show minor expansion at ambient temperatures, but also improved the residual compressive strength, thermal shrinkage resistance and cracking resistance in comparison to unmodified cementitious material. However, due to the viscosity of XG and the coordination of Al and non-terminal carboxyl groups in XG breaking the gel network, XG incorporation should not exceed 1 wt.‱ as the compressive strength and fluidity are decreased.