Boosting Visible Light Photocatalysis: Se Rods Decorated with SnO Nanoparticles.

Se rods decorated with SnO nanoparticles have been synthesized via a facile hydrothermal approach to bridge the gap between ultraviolet-only and visible-only photocatalysis and to enhance reactive oxygen species generation under visible illumination. Structural and morphological analyses using X-ray diffraction and scanning electron microscopy with energy dispersive spectroscopy have confirmed the coexistence of cassiterite SnO particles intimately interfaced with trigonal selenium rods. Diffuse-reflectance spectroscopy revealed a long absorption tail extending into the 400-550 nm range. Under 450 nm sample illumination, the composite produced singlet oxygen in higher yields than either bare SnO or Se, as evidenced by the indocyanine green assay. The system alone does not produce free radicals, as shown by the terephthalic acid test; however, the addition of rhodamine B acts as an effective sensitizer, enabling hydroxyl radical generation. Photodegradation tests using rhodamine B have shown that the SnO-Se system outperforms both its single components, Se and SnO, as a catalyst. The synergistic interplay underscores the potential of SnO-Se heterostructures in photochemical applications under visible light.