Evidence of amino acids in hydrolysates of compounds formed by ionizing radiations. II. Aqueous solutions of CH3CN and C2H5CN.

It has been shown that the action of ionizing radiations on dilute, oxygen-free, aqueous solutions of acetonitrile and propionitrile leads to the formation of oligomers, which upon hydrolyses release amino acids. The presence of nine amino acids, the same as those found in irradiated aqueous cyanides, has been established. those amino acids with asymmetric carbon atoms separated by GC method, appeared to consist of nearly equal amounts of D and L isomers. Glycine is the most abundant amino acid in hydrolysates of acetonitrile, while alanine appears in the samples of propionitrile. A comparison of all amino acids, identified in hydrolysates of various cyanides and nitriles, suggests that it is the cyano group, and a free-radical initiated mechanism, that is primarily involved in these radiation-chemical changes of potential interest to prebiotic chemistry.