Takahashi K, Tomita F
J Antibiot (Tokyo). 1983 Nov;36(11):1531-5. doi: 10.7164/antibiotics.36.1531.
The biosynthesis of the aglycones of gilvocarcins V and M has been studied with 13C-labeled precursors. The aglycones have been shown to be formed via the acetate pathway and a route for their biosynthesis is proposed which involves secondary addition of an alkyl group.
利用13C标记的前体对吉尔瓦菌素V和M的苷元生物合成进行了研究。已证明苷元是通过乙酸途径形成的,并提出了其生物合成途径,该途径涉及烷基的二次添加。