1,5-脱水-D-葡萄糖醇的芳族和杂环1-C-取代衍生物。
Aromatic and heterocyclic 1-C-substituted derivatives of 1,5-anhydro-D-glucitol.
作者信息
Grynkiewicz G, BeMiller J N
出版信息
Carbohydr Res. 1984 Aug 15;131(2):273-6. doi: 10.1016/0008-6215(84)85249-0.
PMID:6488205
Abstract
Reaction of anomeric 1-O-acyl and 1-halide derivatives of 2,3,4,6-tetra-O-benzyl-D-glucose with anisole, ferrocene, thiophene, furan, and 1,3,5-trimethoxybenzene in the presence of a Lewis acid gives the corresponding C-beta-D-glucopyranosyl derivatives.
摘要
2,3,4,6-四-O-苄基-D-葡萄糖的异头1-O-酰基和1-卤化物衍生物与苯甲醚、二茂铁、噻吩、呋喃和1,3,5-三甲氧基苯在路易斯酸存在下反应，生成相应的β-D-吡喃葡萄糖基衍生物。
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