Sostman H E, Manley K A
Clin Chem. 1978 Aug;24(8):1331-4.
We have investigated the equilibrium melting point of gallium as a temperature fixed-point at which to calibrate small thermistor thermometers, such as those used to measure temperature in enzyme reaction analysis and other temperature-dependent biological assays. We have determined that the melting temperature of "6N" (99.999% pure) gallium is 29.770 +/- 0.002 degrees C, and that the constant-temperature plateau can be prolonged for several hours. We have designed a simple automated apparatus that exploits this phenomenon and that permits routine calibration verification of thermistor temperature probes throughout the laboratory day. We describe the physics of the gallium melt, and the design and use of the apparatus.
我们研究了镓的平衡熔点,将其作为一个温度固定点,用于校准小型热敏电阻温度计,比如那些用于酶反应分析及其他温度相关生物测定中测量温度的温度计。我们已确定“6N”(纯度为99.999%)镓的熔点为29.770±0.002摄氏度,且恒温平台可持续数小时。我们设计了一种简单的自动化装置,该装置利用了这一现象,可在整个工作日对实验室中的热敏电阻温度探头进行常规校准验证。我们描述了镓熔体的物理特性以及该装置的设计与使用方法。