用于水相狄尔斯-阿尔德反应中作为双烯体的α-和β-二烯基糖苷的制备。碳水化合物部分对反应热力学的影响。
Preparation of alpha -and beta-dienyl glycosides used as dienes in aqueous Diels-Alder reactions. Influence of the carbohydrate moiety on the thermodynamics of the reaction.
作者信息
Lubineau A, Bienaymé H, Queneau Y
机构信息
Laboratoire de Chimie Organique Multifonctionnelle, Institut de Chimie Moléculaire d'Orsay, Université Paris-Sud, France.
出版信息
Carbohydr Res. 1995 Apr 30;270(2):163-79. doi: 10.1016/0008-6215(95)00019-p.
PMID:7585698
Abstract
A series of 1,3-butadienyl glycosides (mono- and di-saccharides) have been prepared and the kinetics of their Diels-Alder reaction with buten-2-one in water have been studied. The activation parameters for these aqueous cycloadditions provide clues for the hydration structure of such glyco-organic compounds.
摘要
已制备了一系列1,3 - 丁二烯基糖苷（单糖和二糖），并研究了它们在水中与2 - 丁烯酮发生狄尔斯 - 阿尔德反应的动力学。这些水相环加成反应的活化参数为这类糖有机化合物的水合结构提供了线索。
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