Walker G, Keller R, Beckert J, Butte W
Carl von Ossietzky Universität Oldenburg.
Zentralbl Hyg Umweltmed. 1994 Jun;195(5-6):450-6.
Pyrethroids are an analogous substance group to one of the oldest known, naturally occurring insecticides pyrethrum and have replaced a number of pesticides such as Lindane, DDT and PCP on the market. Biocides are more persistent indoors than in nature, which could lead to permanent health hazards for the people concerned. Within a few days after application pyrethroids are rarely detected in room air but can be traced for a long time on textiles, furniture and in dust particles (3, 8). The investigation results of approx. 100 analyses from dust and carpet samples show that approx. 1/3 of these samples are positive for at least one pyrethroid and contain a concentration of > 2 mg substance per kg sample. The evaluation of 35 air samples taken from rooms where substances containing pyrethroids had been used at least a month prior to the investigation (the samples were sampled on active charcoal or Chromosorb) showed that pyrethroids could no longer be traced above the detection limit of 0.05-0.1 micrograms/m3. We therefore think that when investigating a contamination of rooms by biocides it is more advisable to determine pyrethroid and its synergists in the suspended dust portion and corresponding dust sample rather than analysing air by adsorption to active charcoal, Chromosorb or other carrier materials. From the observed concentrations of biocides one could conclude that in an indoor setting secondary contamination by biocides plays a more significant role in the total-body-load than that of air contamination.
拟除虫菊酯是与已知最古老的天然杀虫剂除虫菊类似的一类物质,已取代了市场上的许多农药,如林丹、滴滴涕和五氯苯酚。杀生物剂在室内比在自然环境中更持久,这可能给相关人员带来长期健康危害。施用拟除虫菊酯后的几天内,室内空气中很少能检测到,但在纺织品、家具和灰尘颗粒上能长时间追踪到(3, 8)。对大约100份灰尘和地毯样品的分析结果表明,这些样品中约有三分之一至少对一种拟除虫菊酯呈阳性,且每千克样品中含有浓度>2毫克的该物质。对从至少在调查前一个月使用过含拟除虫菊酯物质的房间采集的35份空气样品(样品采自活性炭或Chromosorb)的评估表明,拟除虫菊酯在检测限0.05 - 0.1微克/立方米以上已无法追踪到。因此,我们认为在调查房间被杀生物剂污染的情况时,更建议测定悬浮灰尘部分及相应灰尘样品中的拟除虫菊酯及其增效剂,而不是通过活性炭、Chromosorb或其他载体材料吸附来分析空气。从观察到的杀生物剂浓度可以得出结论,在室内环境中,杀生物剂的二次污染在全身负荷中比空气污染起的作用更显著。