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钛植入物与牙科合金之间的腐蚀研究。

Study of corrosion between a titanium implant and dental alloys.

作者信息

Reclaru L, Meyer J M

机构信息

Metaux Precieux SA, Neuchatel, Switzerland.

出版信息

J Dent. 1994 Jun;22(3):159-68. doi: 10.1016/0300-5712(94)90200-3.

Abstract

The infiltration of saliva into the multi-metallic structures on titanium implants brings different types of alloys into temporary or permanent contact. In this way a galvanic cell is established as a result of their potential difference. The galvanic cell phenomenon is compounded by another type of corrosion resulting from the geometry of the assembly: localized crevice corrosion. Fifteen galvanic couples (Ti/gold-based alloys, Ti/palladium-based alloy and Ti/non-precious alloys) were studied. Various electrochemical parameters (Ecorr, Ecommon, Ecouple corr, Ecrevice, icorr, icouple corr and Tafel slopes) were analysed. The galvanic currents measured are of the same order of magnitude (except Ti/stainless steel). They remain low. Application of the mixed-potential theory shows that titanium in coupling with the alloys studied will be under either cathodic or anodic control. According to the results obtained, an alloy that is potentially usable for superstructures in a galvanic coupling with titanium must fulfil a certain number of parameters: in a coupling, titanium must have a weak anodic polarization; the current generated by the galvanic cell must also be weak; the crevice potential must be markedly higher than the common potential.

摘要

唾液渗入钛种植体上的多金属结构会使不同类型的合金产生临时或永久接触。这样,由于它们的电位差会形成一个原电池。原电池现象还因组件几何形状导致的另一种腐蚀类型而加剧:局部缝隙腐蚀。研究了15种原电池对(钛/金基合金、钛/钯基合金和钛/非贵金属合金)。分析了各种电化学参数(自腐蚀电位、共同电位、原电池腐蚀电位、缝隙腐蚀电位、腐蚀电流、原电池腐蚀电流和塔菲尔斜率)。所测量的原电池电流处于相同数量级(钛/不锈钢除外)。它们保持在较低水平。混合电位理论的应用表明,与所研究合金耦合的钛将处于阴极或阳极控制之下。根据所得结果,一种在与钛的原电池耦合中可能用于上部结构的合金必须满足一定数量的参数:在耦合中,钛必须具有较弱的阳极极化;原电池产生的电流也必须较弱;缝隙电位必须明显高于共同电位。

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