Iijima Masahiro, Endo Kazuhiko, Yuasa Toshihiro, Ohno Hiroki, Hayashi Kazuo, Kakizaki Mitsugi, Mizoguchi Itaru
Department of Orthodontics, Health Sciences University of Hokkaido, Japan.
Angle Orthod. 2006 Jul;76(4):705-11. doi: 10.1043/0003-3219(2006)076[0705:GCBOOA]2.0.CO;2.
The purpose of this study was to provide a quantitative assessment of galvanic corrosion behavior of orthodontic archwire alloys coupled to orthodontic bracket alloys in 0.9% NaCl solution and to study the effect of surface area ratios. Two common bracket alloys, stainless steels and titanium, and four common wire alloys, nickel-titanium (NiTi) alloy, beta-titanium (beta-Ti) alloy, stainless steel, and cobalt-chromium-nickel alloy, were used. Three different area ratios, 1:1, 1:2.35, and 1:3.64, were used; two of them assumed that the multibracket appliances consists of 14 brackets and 0.016 inch of round archwire or 0.016 x 0.022 inch of rectangular archwire. The galvanic current was measured for 3 successive days using zero-impedance ammeter. When the NiTi alloy was coupled with Ti (1:1, 1:2.35, and 1:3.64 of the surface area ratio) or beta-Ti alloy was coupled with Ti (1:2.35 and 1:3.64 of the surface area ratio), Ti initially was the anode and corroded. However, the polarity reversed in 1 hour, resulting in corrosion of the NiTi or beta-Ti. The NiTi alloy coupled with SUS 304 or Ti exhibited a relatively large galvanic current density even after 72 hours. It is suggested that coupling SUS 304-NiTi and Ti-NiTi may remarkably accelerate the corrosion of NiTi alloy, which serves as the anode. The different anode-cathode area ratios used in this study had little effect on galvanic corrosion behavior.
本研究的目的是对正畸弓丝合金与正畸托槽合金在0.9%氯化钠溶液中的电偶腐蚀行为进行定量评估,并研究表面积比的影响。使用了两种常见的托槽合金,即不锈钢和钛,以及四种常见的弓丝合金,镍钛(NiTi)合金、β钛(β-Ti)合金、不锈钢和钴铬镍合金。使用了三种不同的面积比,1:1、1:2.35和1:3.64;其中两种假设多托槽矫治器由14个托槽和0.016英寸的圆形弓丝或0.016×0.022英寸的矩形弓丝组成。使用零阻抗电流表连续3天测量电偶电流。当NiTi合金与Ti(表面积比为1:1、1:2.35和1:3.64)耦合或β-Ti合金与Ti(表面积比为1:2.35和1:3.64)耦合时,Ti最初是阳极并发生腐蚀。然而,1小时内极性反转,导致NiTi或β-Ti发生腐蚀。即使在72小时后,与SUS 304或Ti耦合的NiTi合金仍表现出相对较大的电偶电流密度。建议耦合SUS 304-NiTi和Ti-NiTi可能会显著加速作为阳极的NiTi合金的腐蚀。本研究中使用的不同阳极-阴极面积比对电偶腐蚀行为影响不大。