Hayakawa Y, Shin-ya K, Furihata K, Seto H
Institute of Molecular and Cellular Biosciences, University of Tokyo, Japan.
J Antibiot (Tokyo). 1993 Oct;46(10):1563-9. doi: 10.7164/antibiotics.46.1563.
The structures of novel macrolide antibiotics, quinolidomicins A1, A2 and B1, were elucidated as shown in Fig. 1 by NMR spectral analysis including a variety of two-dimensional techniques. The quinolidomicins possess a novel 60-membered macrolide ring, which is to our knowledge the largest among natural products.
新型大环内酯类抗生素喹诺利霉素A1、A2和B1的结构通过包括各种二维技术在内的核磁共振光谱分析得以阐明，如图1所示。喹诺利霉素具有一个新型的60元大环内酯环，据我们所知，这是天然产物中最大的。
