Markert B, Herpin U, Siewers U, Berlekamp J, Lieth H
International Graduate School (IHI) Zittau, FRG.
Sci Total Environ. 1996 Apr 5;182(1-3):159-68. doi: 10.1016/0048-9697(95)05028-0.
This is the first attempt to determine pollution with metals throughout the Federal Republic of Germany by analysing moss samples. Samples of Pleurozium schreberi, Scleropodium purum, Hypnum cupessiforme and Hylocomium splendens were collected at 593 sites and analysed by ICP-AES and AAS for the elements As, Cd, Cr, Cu, Fe, Ni, Pb, V and Zn. Citrus leaves and pine needles were used as reference materials to ensure the quality of the results. In many cases it was possible to trace the areas affected by known sources of heavy-metal emissions in addition to isolated local increases in the values. The moss monitoring programme showed up the highly industrialized and urban locations such as the Ruhr, parts of the Saarland and Baden-Wurttemberg and large areas of eastern Germany. Lower levels of many elements were found in wide stretches of Lower Saxony and Bavaria. The results largely reflect the pollution patterns found in these areas. On the other hand, expected correlations between the effects of traffic (e.g. Pb) and concentrations in moss could not be demonstrated with certainty. The element data yielded by this project are Germany's contribution to the European project 'Atmospheric Heavy Metal Deposition in Europe -- Estimations based on Moss Analysis'.
这是首次通过分析苔藓样本确定整个德意志联邦共和国的金属污染情况。在593个地点采集了尖叶泥炭藓、硬叶藓、垂枝藓和华丽泥炭藓的样本,并通过电感耦合等离子体发射光谱法(ICP - AES)和原子吸收光谱法(AAS)分析了其中的砷、镉、铬、铜、铁、镍、铅、钒和锌等元素。使用柑橘叶和松针作为参考材料以确保结果的质量。在许多情况下,除了个别地方的数值升高外,还能够追踪到受已知重金属排放源影响的区域。苔藓监测项目显示出高度工业化和城市化的地区,如鲁尔区、萨尔州和巴登 - 符腾堡州的部分地区以及德国东部的大片区域。在下萨克森州和巴伐利亚州的大片地区,许多元素的含量较低。结果在很大程度上反映了这些地区的污染模式。另一方面,无法确定证明交通影响(如铅)与苔藓中浓度之间预期的相关性。该项目得出的元素数据是德国对欧洲项目“欧洲大气重金属沉积——基于苔藓分析的估算”的贡献。