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[建筑物填缝材料中的多氯联苯(PCB)——柏林现状及新的室内空气来源评估]

[Polychlorinated biphenyls (PCB) in caulking compounds of buildings--assessment of current status in Berlin and new indoor air sources].

作者信息

Fromme H, Baldauf A M, Klautke O, Piloty M, Bohrer L

机构信息

Institut für Umweltanalytik und Humantoxikologie, Berlin.

出版信息

Gesundheitswesen. 1996 Dec;58(12):666-72.

PMID:9081511
Abstract

Since 1990 in Berlin the building blueprints and potaining documents for public utility buildings, in particular schools and child-care centres, have been serutinised and/or buildings have been visited for the possibility of the presence of elastic sealants containing PCB. Pursuant to this, samples of the sealing material of suspected buildings were examined and air in the rooms was measured. Results of measurements (n = 410) in community rooms of schools and child-care centres were an average value of 114 ng/m3 (maximum 7.360 ng/m3) and a geometrical mean of 155 ng/m3. For measurements in schools (n = 308), the geometrical mean was 229 ng/m3, whereas in child-care centres (n = 102) it was 48 ng/m3. Within the framework of the procedural method described above regarding the investigation of suspected buildings, about 15% of the school buildings and 3% of the child-care centres had indoor air values of over 300 ng/m3 (value indicating need for taking precautions) and 5% of the school buildings had more than 3.000 ng/m3 (the value warranting an intervention, according to the now defunct Federal Health Office). No values over 3.000 ng/m3 have been measured up to now in the community rooms of child-care centres. The investigations carried out throughout the Berlin Borough of Tiergarten of all school and child-care centre buildings yielded the results that about 13% of the schools and about 4% of the child-care centres had rooms with air values above 300 ng/m3. Only one school (4%), but none of the child-care centres investigated had values of more than 3.000 ng/m3. We are of the opinion that this proves the need for the creation of an on-target survey of the concrete pollution situation and short-term adoption of exposure-reducing measures or renovations. In any case the exposure of children to this toxicologically suspect substance by this additional way of pollution must be kept as low as possible. In addition to the description of a recently concluded PCB renovation in a school building, another indoor source of pollution is presented which was unknown to date. This is sealing material containing PCB which insulates the pipes of a heating system laid as an insulating floorcover strip near the wall. In the 21 classrooms of the school building, the indoor air concentration in 16 classrooms was 1.000-3.000 ng/m3 and in 5 rooms it was greater than 3.000 ng/m3, with a maximum value of 8.000 ng/m3. In addition, it could be proved for the first time that sealing materials containing PCB were used in the external joints of residential buildings and resulted in indoor air pollution of up to 1.000 ng/m3. The fact that the PCB was also found in sealants which were proved to have been processed even at the beginning of the 1990s, may be of special importance. Up to now, such recent use had always been excluded. Within the framework of the search for contaminated buildings, the time limit regarding the date of construction of the building is no longer adequate. It can be seen from this case in an exemplary fashion, that the removal of waste of the sealants (containing PCB) for the purpose of environmental care is still associated with great problems.

摘要

自1990年起,在柏林,针对公共事业建筑,特别是学校和托儿所的建筑蓝图及相关文件进行了审查,并/或对建筑物进行了走访,以检查是否存在含多氯联苯的弹性密封剂。据此,对疑似建筑物的密封材料样本进行了检测,并对室内空气进行了测量。在学校和托儿所的公共活动室进行的测量结果(n = 410)显示,平均浓度为114 ng/m³(最高7360 ng/m³),几何平均值为155 ng/m³。在学校进行的测量(n = 308)中,几何平均值为229 ng/m³,而在托儿所(n = 102)中为48 ng/m³。在上述针对疑似建筑物的调查程序框架内,约15%的学校建筑和3%的托儿所室内空气值超过300 ng/m³(该值表明需要采取预防措施),5%的学校建筑超过3000 ng/m³(根据现已废止的联邦卫生局的规定,该值需进行干预)。截至目前,在托儿所的公共活动室中尚未检测到超过3000 ng/m³的值。对柏林蒂尔加滕区所有学校和托儿所建筑进行的调查结果显示,约13%的学校和约4%的托儿所的房间空气值高于300 ng/m³。只有一所学校(4%)的测量值超过3000 ng/m³,而在接受调查的托儿所中没有一所超过该值。我们认为,这证明有必要针对具体污染情况进行有针对性的调查,并短期内采取减少接触或翻新的措施。无论如何,必须尽可能降低儿童通过这种额外污染途径接触这种毒理学上可疑物质的风险。除了描述最近在一所学校建筑中完成的多氯联苯翻新工程外,还介绍了另一个迄今为止未知的室内污染源。这是一种含多氯联苯的密封材料,它作为绝缘地板条铺设在靠近墙壁的加热系统管道上。在该学校建筑的21间教室中,16间教室的室内空气浓度为1000 - 3000 ng/m³,5间教室的浓度大于3000 ng/m³,最大值为8000 ng/m³。此外,首次证明含多氯联苯的密封材料用于住宅建筑的外部接缝,导致室内空气污染高达1000 ng/m³。多氯联苯甚至在20世纪90年代初就已被证明用于密封剂中,这一事实可能具有特殊重要性。到目前为止,一直排除这种近期使用的情况。在寻找受污染建筑物的框架内,关于建筑物建造日期的时间限制已不再适用。从这个案例中可以典型地看出,为了环境保护而清除(含多氯联苯的)密封剂废物仍然存在很大问题。

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