Kunzemann J, Herrmann K
Z Lebensm Unters Forsch. 1977 Jul 29;164(3):194-200. doi: 10.1007/BF01263030.
The flavonoid constituents of various spices were separated by means of chromatography on cellulose colums, and the following compounds were obtained crystalline: Quercetin 3-glucuronide from caraway, fennel, anise, and coriander; isoquercitrin from caraway and fennel; rutin from fennel and anise; quercetin 3-O-caffeylglucoside and kaempferol 3-glucoside from caraway; quercetin 3-arabinoside from fennel, and luteolin 7-glucoside, isoorientin and isovitexin from anise. Other constitutents which were however not obtained crystalline, but which could be identified by the usual procedures were kaempferol 3-glucuronide and kaempferol 3-arabinoside in fennel, apigenin 7-glucoside and a luteolin glycoside in anise, and isoquercitrin and rutin in coriander. The glycosides contained in the fruit of the four spices also occur in the leaves. Leaves of caraway and fennel in addition contain isorhammetin glycosides in low concentration.
通过纤维素柱色谱法分离了各种香料中的黄酮类成分,得到了以下结晶化合物:从香菜、小茴香、茴芹和芫荽中得到槲皮素3 - 葡萄糖醛酸苷;从香菜和小茴香中得到异槲皮苷;从小茴香和茴芹中得到芦丁;从香菜中得到槲皮素3 - O - 咖啡酰葡萄糖苷和山奈酚3 - 葡萄糖苷;从小茴香中得到槲皮素3 - 阿拉伯糖苷;从茴芹中得到木犀草素7 - 葡萄糖苷、异荭草素和异牡荆素。然而,其他成分虽未得到结晶,但可通过常规方法鉴定,包括小茴香中的山奈酚3 - 葡萄糖醛酸苷和山奈酚3 - 阿拉伯糖苷、茴芹中的芹菜素7 - 葡萄糖苷和一种木犀草素糖苷,以及芫荽中的异槲皮苷和芦丁。这四种香料果实中含有的糖苷在叶子中也有。香菜和小茴香的叶子还含有低浓度的异鼠李素糖苷。