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用于色谱法和毛细管电泳的电感耦合等离子体质谱检测

Inductively coupled plasma mass spectrometric detection for chromatography and capillary electrophoresis.

作者信息

Sutton K, Sutton R M, Caruso J A

机构信息

Department of Chemistry, University of Cincinnati, OH 45221-0172, USA.

出版信息

J Chromatogr A. 1997 Nov 21;789(1-2):85-126. doi: 10.1016/s0021-9673(97)00970-9.

DOI:10.1016/s0021-9673(97)00970-9
PMID:9440286
Abstract

Inductively coupled plasma mass spectrometry (ICP-MS) is now a well established detection technique for liquid chromatography, gas chromatography, supercritical fluid chromatography and capillary electrophoresis. A review of the literature with particular regard to ICP-MS as a chromatographic and capillary electrophoretic detector is presented. The various modes of chromatography and capillary electrophoresis are discussed and practical descriptions for hyphenating the techniques with the ICP mass spectrometer are given. Sample introduction systems and data acquisition methods are reviewed along with the numerous applications of ICP-MS as a chromatographic detector. In addition, alternative plasma sources, such as the atmospheric and reduced pressure helium microwave-induced plasmas for chromatographic detection are described.

摘要

电感耦合等离子体质谱法(ICP-MS)如今是一种成熟的用于液相色谱、气相色谱、超临界流体色谱和毛细管电泳的检测技术。本文对文献进行了综述,特别关注ICP-MS作为色谱和毛细管电泳检测器的情况。讨论了各种色谱和毛细管电泳模式,并给出了将这些技术与ICP质谱仪联用的实际描述。回顾了样品引入系统和数据采集方法,以及ICP-MS作为色谱检测器的众多应用。此外,还描述了替代等离子体源,如用于色谱检测的常压和减压氦微波诱导等离子体。

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