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双酚A的环境归宿、影响及暴露情况综述。

A review of the environmental fate, effects, and exposures of bisphenol A.

作者信息

Staples C A, Dorn P B, Klecka G M, O'Block S T, Harris L R

机构信息

Assessment Technologies, Inc., Fairfax, VA 22030, USA.

出版信息

Chemosphere. 1998 Apr;36(10):2149-73. doi: 10.1016/s0045-6535(97)10133-3.

Abstract

Bisphenol A (CAS 85-05-7) may be released into the environment through its use and handling, and permitted discharges. BPA is moderately soluble (120 to 300 mg/L at pH 7), may adsorb to sediment (Koc 314 to 1524), has low volatility, and is not persistent based on its rapid biodegradation in acclimated wastewater treatment plants and receiving waters (half-lives 2.5 to 4 days). BPA is "slightly to moderately" toxic (algal EC50 of 1000 micrograms/L) and has low potential for bioaccumulation in aquatic organisms (BCFs 5 to 68). The chronic NOEC for Daphnia magna is > 3146 micrograms/L. Surface water concentrations are at least one to several orders of magnitude lower than chronic effects, with most levels nondetected.

摘要

双酚A(CAS 85-05-7)可能通过其使用、处理及允许排放进入环境。双酚A在pH值为7时溶解度适中(120至300毫克/升),可能吸附于沉积物(分配系数Koc为314至1524),挥发性低,且由于其在驯化的污水处理厂和受纳水体中能快速生物降解(半衰期为2.5至4天),所以不具持久性。双酚A具有“轻度至中度”毒性(藻类半数效应浓度EC50为1000微克/升),在水生生物中的生物累积潜力较低(生物富集系数BCF为5至68)。大型溞的慢性无可见效应浓度(NOEC)大于3146微克/升。地表水浓度至少比慢性效应低一至几个数量级,大多数水平未被检测到。

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