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在潜在的前生物条件下核苷5'-多磷酸的形成。

Formation of nucleoside 5'-polyphosphates under potentially prebiological conditions.

作者信息

Lohrmann R

出版信息

J Mol Evol. 1976 Oct 27;8(3):197-210. doi: 10.1007/BF01730997.

DOI:10.1007/BF01730997
PMID:978748
Abstract

Aqueous solutions of linear inorganic polyphosphates incubated in presence of Mg ions depolymerize to give trimetaphosphate. The presence of a nucleoside 5'-phosphate has little influence upon the reaction. Drying the products obtained by incubating a linear polyphosphate with Mg ions in the presence of a nucleoside 5'-phosphate yields nucleoside 5'-polyphosphates. The prebiological relevance of the reactions is discussed.

摘要

在镁离子存在下孵育的线性无机多磷酸盐水溶液解聚生成三聚磷酸。核苷5'-磷酸的存在对该反应影响很小。将线性多磷酸盐与镁离子在核苷5'-磷酸存在下孵育所得到的产物进行干燥，可得到核苷5'-多磷酸盐。本文讨论了这些反应在生命起源前的相关性。

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1
Formation of nucleoside 5'-polyphosphates under potentially prebiological conditions.在潜在的前生物条件下核苷5'-多磷酸的形成。
J Mol Evol. 1976 Oct 27;8(3):197-210. doi: 10.1007/BF01730997.
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Formation of nucleoside 5'-polyphosphates from nucleotides and trimetaphosphate.
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本文引用的文献

1
DISMUTATION REACTIONS OF NUCLEOSIDE POLYPHOSPHATES. I. GENERAL FEATURES OF THE REACTION.核苷多磷酸盐的歧化反应。I. 反应的一般特征
J Am Chem Soc. 1965 May 20;87:2257-65. doi: 10.1021/ja01088a027.
2
Phosphorylation by way of inorganic phosphate as a potential prebiotic process.
Nature. 1968 May 4;218(5140):442-3. doi: 10.1038/218442a0.
3
Further studies of urea-catalyzed phosphorylation reactions.尿素催化的磷酸化反应的进一步研究。
J Mol Evol. 1973;2(2-3):231-4. doi: 10.1007/BF01654004.
以硫酯N，S-二乙酰基半胱胺作为缩合剂形成焦磷酸、三聚磷酸和磷酰咪唑。
J Mol Evol. 1981;18(1):24-9. doi: 10.1007/BF01733208.
4
Trace elements in chemical evolution, I.
Orig Life Evol Biosph. 1985;16(1):41-55. doi: 10.1007/BF01808048.
5
Formation of nucleoside 5'-phosphoramidates under potentially prebiological conditions.
J Mol Evol. 1977 Nov 25;10(2):137-54. doi: 10.1007/BF01751807.
6
Formation of P1, P2-dinucleoside 5'-pyrophosphates under potentially prebiological conditions.
J Mol Evol. 1978 May 12;11(1):17-23. doi: 10.1007/BF01768021.
4
Polyphosphate and trimetaphosphate formation under potentially prebiotic conditions.在潜在的益生元条件下多聚磷酸盐和三聚偏磷酸盐的形成。
J Mol Evol. 1972;1(3):241-8. doi: 10.1007/BF01660243.
5
The effect of Mg2+ and Ca2+ on urea-catalyzed phosphorylation reactions.
J Mol Evol. 1973 Nov 27;2(4):251-62. doi: 10.1007/BF01654094.
6
On the possible role of crystals in the origins of life. IV. The phosphorylation of nucleotides.论晶体在生命起源中的可能作用。IV. 核苷酸的磷酸化作用
Curr Mod Biol. 1970 Jul;3(3):277-83. doi: 10.1016/0303-2647(70)90010-9.
7
Formation of nucleoside 5'-polyphosphates from nucleotides and trimetaphosphate.
J Mol Evol. 1975 Dec 29;6(4):237-52. doi: 10.1007/BF01794633.