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腺苷 -5'- 基亚氨二磷酸的质子和金属配合物。

The proton and metal complexes of adenyl-5'-yl imidodiphosphate.

作者信息

Pettit L D, Siddiqui K F

出版信息

Biochem J. 1976 Oct 1;159(1):169-71. doi: 10.1042/bj1590169.

DOI:10.1042/bj1590169
PMID:999636
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC1164052/
Abstract

The formation constants of the complexes of adenyl-5'-yl imidodiphosphate with H+ Mg2+, Ca2+ and a number of bivalent transition-metal ions were measured potentionmetrically. The complexes are generally a little more stable than the analogous complexes of ATP. By measuring the formation constants at two temperatures, this increase in stability was shown to result from an increased enthalpy change on complex-formation.

摘要

通过电位滴定法测定了腺苷 - 5'-亚氨基二磷酸与H⁺、Mg²⁺、Ca²⁺以及多种二价过渡金属离子形成配合物的形成常数。这些配合物通常比ATP的类似配合物稍稳定一些。通过在两个温度下测量形成常数,结果表明这种稳定性的增加是由于配合物形成时焓变增加所致。

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本文引用的文献

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Thermodynamic studies of the formation and ionization of the magnesium(II) complexes of ADP and ATP over the pH range 5 to 9.在pH值5至9范围内对ADP和ATP的镁(II)配合物的形成和电离进行的热力学研究。
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Biochemistry. 1971 Jun 22;10(13):2490-6. doi: 10.1021/bi00789a010.
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Nitrogenase in Azotobacter chroococcum and Klebsiella pneumoniae.褐球固氮菌和肺炎克雷伯氏菌中的固氮酶。
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