Two new taxane diterpenoids from the seeds of the Chinese yew, Taxus yunnanensis.

作者信息

Shi Q W, Oritani T, Sugiyama T, Murakami R, Yamada T

机构信息

Laboratory of Applied Bioorganic Chemistry, Division of Life Sciences, Graduate School of Agricultural Science, Tohoku University, 1-1 Tsutsumi-dori Amamiya, Aoba-ku, Sendai 981-8555, Japan.

出版信息

J Asian Nat Prod Res. 1999;2(1):71-9. doi: 10.1080/10286029908039894.

DOI:10.1080/10286029908039894

PMID:11261209

Abstract

A new taxoid and a taxinine analogue were isolated from the seeds of the Chinese yew, Taxus yunnanensis. The structures were established as 13 alpha-acetoxy-5 alpha-(3'-dimethylamino-3'-phenyl)-propionyloxy-11(15-->1)-abeotaxa- 4(20),11-diene-9 alpha, 10 beta-diol and 2 alpha-acetoxy-5 alpha-cinnamoyloxy-9 alpha, 10 beta-dihydroxy-taxa- 4(20),11-diene-13-one on the basis of 1D, 2D NMR, and MS spectral analysis.

摘要