一种三核异双金属钌（II）/铂（II）配合物作为对含巯基氨基酸和肽具有选择性的化学计量计。
A trinuclear heterobimetallic Ru(II)/Pt(II) complex as a chemodosimeter selective for sulfhydryl-containing amino acids and peptides.
作者信息
Chow Cheuk-Fai, Chiu Brenda K W, Lam Michael H W, Wong Wai-Yeung
机构信息
Department of Biology and Chemistry, City University of Hong Kong, 83 Tat Chee Avenue, Hong Kong SAR, China.
出版信息
J Am Chem Soc. 2003 Jul 2;125(26):7802-3. doi: 10.1021/ja034891x.
A trinuclear heterobimetallic Ru(II)/Pt(II) complex, cis-{Ru(phen)2[CN-Pt(DMSO)Cl2]2} (phen = 1,10-phenanthroline), is able to function as a "switch-on" luminescent chemodosimeter for sulfhydryl-containing amino acids and peptides via specific binding of the amino acids/peptides with the Pt(II) centers and the subsequent cleavage of the Ru(II)-Pt(II) cyano-bridge.
一种三核异双金属钌（II）/铂（II）配合物，顺式-{Ru（邻菲罗啉）₂[CN-Pt（二甲基亚砜）Cl₂]₂}（邻菲罗啉 = 1,10-菲咯啉），能够通过含硫氨基酸和肽与铂（II）中心的特异性结合以及随后钌（II）-铂（II）氰基桥的断裂，作为一种用于含巯基氨基酸和肽的“开启”发光化学传感器。
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