Díaz-Requejo M Mar, Belderraín Tomás R, Nicasio M Carmen, Trofimenko Swiatoslaw, Pérez Pedro J
Departamento de Química y Ciencia de Materiales, Universidad de Huelva, Campus de El Carmen, 21071-Huelva, Spain.
J Am Chem Soc. 2003 Oct 8;125(40):12078-9. doi: 10.1021/ja037072l.
The complex TpBr3Cu(NCMe) catalyzes, at room temperature, the insertion of a nitrene group from PhINTs into the carbon-hydrogen bond of cyclohexane and benzene, as well as into the primary C-H bonds of the methyl groups of toluene and mesitylene, in moderate to high yield.
络合物TpBr3Cu(NCMe)在室温下催化，使来自PhINTs的氮烯基团插入环己烷和苯的碳氢键，以及甲苯和均三甲苯甲基的一级碳氢键中，产率适中至高。
