Pfleiderer C, Reznik D, Pintschovius L, Löhneysen H V, Garst M, Rosch A
Physikalisches Institut, Universität Karlsruhe, D-76128 Karlsruhe, Germany.
Nature. 2004 Jan 15;427(6971):227-31. doi: 10.1038/nature02232.
Only a few metallic phases have been identified in pure crystalline materials. These include normal, ferromagnetic and antiferromagnetic metals, systems with spin and charge density wave order, and superconductors. Fermi-liquid theory provides a basis for the description of all of these phases. It has been suggested that non-Fermi-liquid phases of metals may exist in some heavy-fermion compounds and oxide materials, but the discovery of a characteristic microscopic signature of such phases presents a major challenge. The transition-metal compound MnSi above a certain pressure (p(c) = 14.6 kbar) provides what may be the cleanest example of an extended non-Fermi-liquid phase in a three-dimensional metal. The bulk properties of MnSi suggest that long-range magnetic order is suppressed at p(c) (refs 7-12). Here we report neutron diffraction measurements of MnSi, revealing that sizeable quasi-static magnetic moments survive far into the non-Fermi-liquid phase. These moments are organized in an unusual pattern with partial long-range order. Our observation supports the existence of novel metallic phases with partial ordering of the conduction electrons (reminiscent of liquid crystals), as proposed for the high-temperature superconductors and heavy-fermion compounds.
在纯晶体材料中仅发现了少数金属相。这些包括普通金属、铁磁金属和反铁磁金属、具有自旋和电荷密度波序的体系以及超导体。费米液体理论为描述所有这些相提供了基础。有人提出,金属的非费米液体相可能存在于一些重费米子化合物和氧化物材料中,但发现此类相的特征微观特征是一个重大挑战。过渡金属化合物MnSi在高于一定压力(p(c)=14.6千巴)时,可能是三维金属中扩展非费米液体相最纯粹的例子。MnSi的体性质表明,在p(c)时,长程磁序受到抑制(参考文献7-12)。在此,我们报告了对MnSi的中子衍射测量结果,揭示出相当大的准静态磁矩在非费米液体相中能持续存在很远距离。这些磁矩以一种具有部分长程有序的不寻常模式排列。我们的观察结果支持了存在具有传导电子部分有序的新型金属相(类似于液晶)的观点,这一观点已针对高温超导体和重费米子化合物提出。