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来自小叶豆腐柴的新型甘油糖脂和神经酰胺。

New glyceroglycolipid and ceramide from Premna microphylla.

作者信息

Zhan Zha-Jun, Yue Jian-Min

机构信息

State Key Laboratory of Drug Research, Shanghai Institute for Biological Sciences, Chinese Academy of Sciences, Zhangjiang Hi-Tech Park, Shanghai 201203, People's Republic of China.

出版信息

Lipids. 2003 Dec;38(12):1299-303. doi: 10.1007/s11745-003-1193-7.

Abstract

Two new compounds (1,2) were isolated from the ethanolic extract of the leaves of Premna microphylla, together with five known compounds. The structures of compounds 1 and 2 were elucidated as (2S,3S,4R,11E)-2-[(2R)-2-hydroxytetracosanoylaminol-11-octadecene-1,3,4-triol (1) and 1-O-(9Z,12Z, 15Z-octadecatrienoyl)-3-O-[beta-D-galactopyranosyl-(1 --> 6)- O-beta-D-galactopyranosyl-(1 --> 6)-alpha-D-galactopyranosyl] glycerol (2) by means of spectroscopic and chemical methods.

摘要

从豆腐柴叶的乙醇提取物中分离出两种新化合物(1,2)以及五种已知化合物。通过光谱和化学方法确定化合物1和2的结构分别为(2S,3S,4R,11E)-2-[(2R)-2-羟基二十四烷酰胺基]-11-十八碳烯-1,3,4-三醇(1)和1-O-(9Z,12Z,15Z-十八碳三烯酰基)-3-O-[β-D-吡喃半乳糖基-(1→6)-O-β-D-吡喃半乳糖基-(1→6)-α-D-吡喃半乳糖基]甘油(2)。

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