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水生拉恩菌1-95脂多糖O-多糖的结构

Structure of the O-polysaccharide of the lipopolysaccharide of Rahnella aquatilis 1-95.

作者信息

Zdorovenko Evelina L, Varbanets Ludmila D, Zatonsky George V, Ostapchuk Andrey N

机构信息

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospekt 47, 119991 Moscow, Russia.

出版信息

Carbohydr Res. 2004 Jul 12;339(10):1809-12. doi: 10.1016/j.carres.2004.05.011.

Abstract

The O-polysaccharide was isolated by mild acid hydrolysis of the lipopolysaccharide of Rahnella aquatilis 1-95 and studied by sugar and methylation analyses along with 1H and 13C NMR spectroscopy, including NOESY and 1H,13C HSQC experiments for linkage and sequence analysis. The following structure of the branched trisaccharide repeating unit of the O-polysaccharide was established: [carbohydrate structure: see text].

摘要

通过对水生拉恩氏菌1-95脂多糖进行温和酸水解分离出O-多糖,并通过糖分析、甲基化分析以及1H和13C NMR光谱进行研究,包括用于连接和序列分析的NOESY和1H,13C HSQC实验。确定了O-多糖支链三糖重复单元的以下结构:[碳水化合物结构:见正文]

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