CuBr催化的与氮原子相邻的sp3 C-H键的高效炔基化反应。
CuBr-catalyzed efficient alkynylation of sp3 C-H bonds adjacent to a nitrogen atom.
作者信息
Li Zhiping, Li Chao-Jun
机构信息
Department of Chemistry, McGill University, 801 Sherbrooke Street West, Montreal, Quebec H3A 2K6, Canada.
出版信息
J Am Chem Soc. 2004 Sep 29;126(38):11810-1. doi: 10.1021/ja0460763.
PMID:15382913
Abstract
A simple and effective catalytic method to construct propargylamine was developed by using copper bromide and tert-BuOOH via a combination of sp3 C-H bond and sp C-H bond activations followed by C-C bond formation.
摘要
通过溴化铜和叔丁基过氧化氢，结合sp3 C-H键和sp C-H键活化，随后形成C-C键，开发了一种简单有效的构建炔丙胺的催化方法。
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