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用硫酸铁还原水泥中的铬酸盐。

Reduction of chromate in cement by iron sulfate.

作者信息

Fregert S, Gruvberger B, Sandahl E

出版信息

Contact Dermatitis. 1979 Jan;5(1):39-42. doi: 10.1111/j.1600-0536.1979.tb05533.x.

DOI:10.1111/j.1600-0536.1979.tb05533.x
PMID:154387
Abstract

Cement dermatitis is connected with chromate sensitivity. It can therefore be expected that "elimination" of chromate in cement would decrease the number of cases of cement dermatitis. Iron sulfate added to cement reduces the chromate completely and the 3-valent chromium is precipitated. An amount of 0.35% (w/w) iron sulfate, FeSO4 . 7H2O, is enough to reduce 20 microgram Cr6+/g cement. There is no technical side effect to the concrete. The iron sulfate is preferably added to cement when there is an intimate contact with skin, e.g. at floor laying, repairs and hand-made casting.

摘要

水泥性皮炎与铬酸盐过敏有关。因此可以预期,水泥中铬酸盐的“去除”将减少水泥性皮炎的病例数量。添加到水泥中的硫酸铁可完全还原铬酸盐,三价铬会沉淀下来。0.35%(重量/重量)的七水合硫酸亚铁(FeSO₄·7H₂O)足以将每克水泥中的20微克六价铬还原。对混凝土没有技术方面的副作用。在与皮肤有密切接触的情况下,例如在铺设地板、维修和手工浇铸时,最好将硫酸铁添加到水泥中。

相似文献

1
Reduction of chromate in cement by iron sulfate.用硫酸铁还原水泥中的铬酸盐。
Contact Dermatitis. 1979 Jan;5(1):39-42. doi: 10.1111/j.1600-0536.1979.tb05533.x.
2
Prevention of cement dermatitis in construction workers with iron sulphate.用硫酸亚铁预防建筑工人的水泥性皮炎。
Asia Pac J Public Health. 1987;1(1):91-3. doi: 10.1177/101053958700100119.
3
Prevalence of cement eczema in Denmark before and since addition of ferrous sulfate to Danish cement.
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Chromate sensitization and elicitation from cement with iron sulfate.
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[Elimination of chromate in cement].[水泥中铬酸盐的去除]
Z Gesamte Hyg. 1980;26(9):625-8.
6
Change in cement manufacturing process, a cause for decline in chromate allergy?水泥制造工艺的改变是铬酸盐过敏率下降的一个原因吗?
Contact Dermatitis. 1996 Jan;34(1):51-4. doi: 10.1111/j.1600-0536.1996.tb02112.x.
7
Has European Union legislation to reduce exposure to chromate in cement been effective in reducing the incidence of allergic contact dermatitis attributed to chromate in the UK?欧盟减少水泥中六价铬暴露的立法是否有效降低了英国归因于六价铬的过敏性接触性皮炎的发病率?
Occup Environ Med. 2012 Feb;69(2):150-2. doi: 10.1136/oemed-2011-100220. Epub 2011 Aug 17.
8
Patch testing with cement containing iron sulfate.
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Factors decreasing the content of water-soluble chromate in cement.降低水泥中水溶性铬酸盐含量的因素。
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Risk factors for cement eczema.骨水泥湿疹的危险因素。
Contact Dermatitis. 1991 Aug;25(2):81-8. doi: 10.1111/j.1600-0536.1991.tb01793.x.

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Occupational contact allergy in the building trade in Germany: influence of preventive measures and changing exposure.
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Occupational medicine-important advances in clinical medicine: prevention of cement allergy.职业医学——临床医学的重要进展:水泥过敏的预防
West J Med. 1983 Aug;139(2):213.
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Occupational skin-disease data in Europe.欧洲的职业性皮肤病数据。
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