Xu Xiaoyou, Ray Robert, Gu Yunlong, Ploehn Harry J, Gearheart Latha, Raker Kyle, Scrivens Walter A
Department of Chemistry & Biochemistry, Department of Chemical Engineering and USC Nanocenter, University of South Carolina, 631 Sumter Street, SC 29208, USA.
J Am Chem Soc. 2004 Oct 13;126(40):12736-7. doi: 10.1021/ja040082h.
Arc-synthesized single-walled carbon nanotubes have been purified through preparative electrophoresis in agarose gel and glass bead matrixes. Two major impurities were isolated: fluorescent carbon and short tubular carbon. Analysis of these two classes of impurities was done. The methods described may be readily extended to the separation of other water-soluble nanoparticles. The separated fluorescent carbon and short tubule carbon species promise to be interesting nanomaterials in their own right.
电弧合成的单壁碳纳米管已通过在琼脂糖凝胶和玻璃珠基质中的制备性电泳进行了纯化。分离出了两种主要杂质:荧光碳和短管状碳。对这两类杂质进行了分析。所描述的方法可以很容易地扩展到其他水溶性纳米颗粒的分离。分离出的荧光碳和短管碳物种本身有望成为有趣的纳米材料。