Davis Franklin A, Wu Yongzhong, Xu He, Zhang Junyi
Department of Chemistry, Temple University, Philadelphia, PA 19122, USA.
Org Lett. 2004 Nov 25;6(24):4523-5. doi: 10.1021/ol048157+.
Cis-5-substituted pyrrolidine phosphonates, proline surrogates, are prepared by a highly stereoselective intramolecular metal carbenoid N-H insertion from a sulfinimine-derived delta-amino alpha-diazo beta-ketophosphonate. [reaction: see text]
顺式-5-取代吡咯烷膦酸酯类脯氨酸替代物，是通过一种高度立体选择性的分子内金属卡宾体对亚磺酰亚胺衍生的δ-氨基α-重氮β-酮膦酸酯进行N-H插入反应制备而成。[反应：见正文]
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