Yeung King Lun, Yao Nan
Department of Chemical Engineering, the Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, People's Republic of China.
J Nanosci Nanotechnol. 2004 Sep;4(7):647-90. doi: 10.1166/jnn.2004.097.
This review discusses the recent progress in the application of scanning probe microscopy (SPM) in catalysis. SPM proves to be an invaluable technique for imaging catalytic surfaces and interfaces. Most SPM research is related to the structural and morphological transformation associated with catalyst preparation and use. Real-time SPM observation of surface dynamics including adsorption, diffusion and reaction, provides invaluable insights to the mechanism of catalysis. SPM is also used to shape and manipulate surfaces and surface processes. Fabrication of nanostructured catalysts, direct manipulation of adsorbed atoms and molecules and tip-mediated reactions are some examples of new SPM approach in catalyst research.
本综述讨论了扫描探针显微镜(SPM)在催化领域应用的最新进展。事实证明,SPM是用于催化表面和界面成像的一项极具价值的技术。大多数SPM研究都与催化剂制备和使用过程中相关的结构和形态转变有关。对包括吸附、扩散和反应在内的表面动力学进行实时SPM观测,为催化机理提供了极有价值的见解。SPM还可用于塑造和操控表面及表面过程。纳米结构催化剂的制备、对吸附原子和分子的直接操控以及针尖介导反应,都是催化剂研究中SPM新方法的一些实例。