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纳米氧化镁的可控制备及其杀菌性能研究

Controllable preparation of Nano-MgO and investigation of its bactericidal properties.

作者信息

Huang Lei, Li Dian-Qing, Lin Yan-Jun, Wei Min, Evans David G, Duan Xue

机构信息

Key Laboratory of Science and Technology of Controllable Chemical Reactions, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029, PR China.

出版信息

J Inorg Biochem. 2005 May;99(5):986-93. doi: 10.1016/j.jinorgbio.2004.12.022.

Abstract

Samples of nano-MgO with varying particle sizes were prepared by four different methods using Mg(NO3)2.6H2O, Na2CO3, urea and ammonia as raw materials and characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), low temperature N2 adsorption-desorption measurements and FT-IR spectroscopy. Bactericidal experiments with Bacillus subtilis var. niger and Staphylococcus aureus were carried out using as-synthesized nano-MgO samples and the bactericidal mechanism was also investigated. The results showed that the bactericidal efficacy of nano-MgO increases with decreasing particle size. The bactericidal efficacy of the samples was compared with that of TiO2, a common photoactive bactericidal material. The nano-MgO has better bactericidal activity, both when used directly and as an additive in an interior wall paint. Furthermore, nano-MgO is active even in the absence of irradiation.

摘要

以Mg(NO₃)₂·6H₂O、Na₂CO₃、尿素和氨水为原料,采用四种不同方法制备了不同粒径的纳米MgO样品,并通过X射线衍射(XRD)、透射电子显微镜(TEM)、低温N₂吸附-脱附测量和傅里叶变换红外光谱(FT-IR)对其进行了表征。使用合成的纳米MgO样品对枯草芽孢杆菌黑色变种和金黄色葡萄球菌进行了杀菌实验,并对杀菌机制进行了研究。结果表明,纳米MgO的杀菌效果随粒径减小而增强。将样品的杀菌效果与常见的光活性杀菌材料TiO₂进行了比较。纳米MgO无论是直接使用还是作为内墙涂料中的添加剂,都具有更好的杀菌活性。此外,纳米MgO即使在没有光照的情况下也具有活性。

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