轴手性双（硫醇盐）配体的钇配合物催化的对映选择性分子内烯烃氢胺化反应。
Enantioselective intramolecular alkene hydroaminations catalyzed by yttrium complexes of axially chiral bis(thiolate) ligands.
作者信息
Kim Joon Young, Livinghouse Tom
机构信息
Department of Chemistry, Montana State University, Bozeman, Montana 59717, USA.
出版信息
Org Lett. 2005 Apr 28;7(9):1737-9. doi: 10.1021/ol050294z.
PMID:15844894
Abstract
[structure: see text] A yttrium(III) complex derived from proligand 7c has been shown to be a superior catalyst for enantioselective intramolecular alkene hydroaminations that provide cyclic amines with ee's ranging from 69% to 89%.
摘要
[结构：见原文] 已证明一种由前体配体7c衍生的钇（III）配合物是对映选择性分子内烯烃氢胺化反应的优良催化剂，该反应能提供对映体过量值（ee）在69%至89%之间的环状胺。
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