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光果甘草叶中的二氢茋衍生物。

Dihydrostilbene derivatives from Glycyrrhiza glabra leaves.

作者信息

Biondi Daniela M, Rocco Concetta, Ruberto Giuseppe

机构信息

Istituto del C.N.R. di Chimica Biomolecolare, Sezione di Catania, Via del Santuario 110, I-95028 Valverde CT, Italy.

出版信息

J Nat Prod. 2005 Jul;68(7):1099-102. doi: 10.1021/np050034q.

DOI:10.1021/np050034q
PMID:16038558
Abstract

Four new dihydrostilbenes, alpha,alpha'-dihydro-3,5-dihydroxy-4'-acetoxy-5'-isopentenylstilbene (1), alpha,alpha'-dihydro-3,3',4'-trihydroxy-5-O-isopentenyl-6-isopentenylstilbene (2), alpha,alpha'-dihydro-3,5,3'-trihydroxy-4'-methoxystilbene (3), and alpha,alpha'-dihydro-3,3'-dihydroxy-5beta-d-O-glucopyranosyloxy-4'-methoxystilbene (4), together with seven known flavonoids, glabranin isomer, naringenin, lupiwighteone, pinocembrin 7-O-glucoside, astragalin, isoquercitrin, vicenin II, and the inositol, pinitol, were isolated from the leaves of Glycyrrhiza glabra grown in Sicily. The structures of 1-4 were elucidated by spectroscopic methods.

摘要

从生长在西西里岛的光果甘草叶中分离出4种新的二氢茋类化合物,即α,α'-二氢-3,5-二羟基-4'-乙酰氧基-5'-异戊烯基茋(1)、α,α'-二氢-3,3',4'-三羟基-5-O-异戊烯基-6-异戊烯基茋(2)、α,α'-二氢-3,5,3'-三羟基-4'-甲氧基茋(3)和α,α'-二氢-3,3'-二羟基-5β-d-O-吡喃葡萄糖氧基-4'-甲氧基茋(4),以及7种已知的黄酮类化合物,即光甘草定异构体、柚皮素、羽扇豆黄烷酮紫檀素、松属素7-O-葡萄糖苷、紫云英苷、异槲皮苷、异荭草苷II,还有肌醇、松醇。通过光谱方法阐明了1-4的结构。

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