Liu Ping, Wu Yiliang, Li Yuning, Ong Beng S, Zhu Shiping
Materials Design & Integration Laboratory, Xerox Research Centre of Canada, Mississauga, Ontario, Canada.
J Am Chem Soc. 2006 Apr 12;128(14):4554-5. doi: 10.1021/ja060620l.
A novel solution-processed, compositionally and structurally stable dual-layer gate dielectric composed of a UV-cured poly(4-vinyl phenol)-co-poly(methyl methacrylate) bottom layer and a thermally cross-linked poly(methyl silsesquioxane) top layer for organic thin-film transistors is described. This gate dielectric design, coupled with compatible solution-processable semiconductor and conductor materials, has enabled fabrication of all solution-processed, high-performance organic thin-film transistors on flexible substrates. High field-effect mobility and current on/off ratio, together with other desirable transistor properties, are demonstrated.
描述了一种新型的溶液处理的、组成和结构稳定的双层栅极电介质,其由用于有机薄膜晶体管的紫外光固化聚(4-乙烯基苯酚)-共聚(甲基丙烯酸甲酯)底层和热交联聚(甲基倍半硅氧烷)顶层组成。这种栅极电介质设计,与兼容的可溶液处理的半导体和导体材料相结合,能够在柔性基板上制造全溶液处理的高性能有机薄膜晶体管。展示了高场效应迁移率和电流开/关比,以及其他理想的晶体管特性。