Liu Xin-Yuan, Li Cheng-Hui, Che Chi-Ming
Department of Chemistry and Open Laboratory of Chemical Biology of the Institute of Molecular Technology for Drug Discovery and Synthesis, The University of Hong Kong, PR China.
Org Lett. 2006 Jun 22;8(13):2707-10. doi: 10.1021/ol060719x.
[reaction: see text] Phosphine gold(I) complexes catalyzed isomerization of terminal alkenes and hydroamination of unactivated alkenes under thermal and microwave-assisted conditions. This is the first example of the use of microwave radiation as a heat source for gold(I)-catalyzed organic reactions.
[反应：见正文] 膦金（I）配合物在热和微波辅助条件下催化末端烯烃的异构化以及未活化烯烃的氢胺化反应。这是首次将微波辐射用作金（I）催化有机反应的热源的实例。
