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同性电荷壁之间的吸引力:使用局域分子场理论的短程模拟。

Attraction between like-charged walls: Short-ranged simulations using local molecular field theory.

作者信息

Rodgers Jocelyn M, Kaur Charanbir, Chen Yng-Gwei, Weeks John D

机构信息

Institute for Physical Science and Technology, University of Maryland, College Park, Maryland 20742, USA.

出版信息

Phys Rev Lett. 2006 Sep 1;97(9):097801. doi: 10.1103/PhysRevLett.97.097801. Epub 2006 Aug 28.

Abstract

Effective attraction between like-charged walls mediated by counterions is studied using local molecular field (LMF) theory. Monte Carlo simulations of the "mimic system" given by LMF theory, with short-ranged "Coulomb core" interactions in an effective single particle potential incorporating a mean-field average of the long-ranged Coulomb interactions, provide a direct test of the theory, and are in excellent agreement with more complex simulations of the full Coulomb system by Moreira and Netz [Eur. Phys. J. E 8, 33 (2002)]. A simple, generally applicable criterion to determine the consistency parameter sigma(min) needed for accurate use of the LMF theory is presented.

摘要

利用局域分子场(LMF)理论研究了由反离子介导的同性带电壁之间的有效吸引力。对LMF理论给出的“模拟系统”进行蒙特卡罗模拟,在包含长程库仑相互作用平均场平均值的有效单粒子势中具有短程“库仑核”相互作用,为该理论提供了直接检验,并且与莫雷拉和内茨对完整库仑系统进行的更复杂模拟[《欧洲物理杂志E》8, 33 (2002)] 高度吻合。提出了一个简单的、普遍适用的准则,用于确定准确使用LMF理论所需的一致性参数σ(min)。

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