钯催化的炔烃氢膦化反应：获得对映体富集的P-手性乙烯基膦硼烷。
Pallado-catalysed hydrophosphination of alkynes: access to enantio-enriched P-stereogenic vinyl phosphine-boranes.
作者信息
Join Benoît, Mimeau David, Delacroix Olivier, Gaumont Annie-Claude
机构信息
Laboratoire de Chimie Moléculaire et Thio-organique, UMR CNRS 6507, ENSI-CAEN, and Université de Caen, 6 bd du Maréchal Juin, 14050 Caen, France.
出版信息
Chem Commun (Camb). 2006 Aug 14(30):3249-51. doi: 10.1039/b607434k. Epub 2006 Jun 26.
DOI:10.1039/b607434k
PMID:17028759
Abstract
Preliminary results dealing with the synthesis of non-racemic P-stereogenic vinylphosphine-boranes by hydrophosphination of alkynes in the presence of a chiral catalyst are reported.
摘要
报道了在手性催化剂存在下，通过炔烃的氢膦化反应合成非外消旋P-手性乙烯基膦硼烷的初步结果。
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