噻唑衍生的N-杂环卡宾催化醛与未活化亚胺的交叉偶联反应。
Thiazolium-derived N-heterocyclic carbene-catalyzed cross-coupling of aldehydes with unactivated imines.
作者信息
Li Gong-Qiang, Dai Li-Xin, You Shu-Li
机构信息
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, P. R. China.
出版信息
Chem Commun (Camb). 2007 Feb 28(8):852-4. doi: 10.1039/b611646a. Epub 2006 Nov 23.
DOI:10.1039/b611646a
PMID:17308653
Abstract
Cross-coupling of aromatic aldehydes or benzoins with unactivated imines catalyzed by an N-heterocyclic carbene (NHC) affords alpha-amino ketones smoothly.
摘要
由氮杂环卡宾（NHC）催化的芳香醛或安息香与未活化亚胺的交叉偶联反应能顺利生成α-氨基酮。
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