以过氧化氢为主要氧化剂的N-芳基取代含恶唑烷酮的酮催化不对称环氧化反应。
An N-aryl-substituted oxazolidinone-containing ketone-catalyzed asymmetric epoxidation with hydrogen peroxide as the primary oxidant.
作者信息
Burke Christopher P, Shu Lianhe, Shi Yian
机构信息
Department of Chemistry, Colorado State University, Fort Collins, CO 80523, USA.
出版信息
J Org Chem. 2007 Aug 3;72(16):6320-3. doi: 10.1021/jo0708644. Epub 2007 Jul 10.
PMID:17622173
Abstract
Asymmetric epoxidation of various olefins with an N-aryl-substituted oxazolidinone-containing ketone as catalyst and hydrogen peroxide as the primary oxidant has been investigated, and up to 96% ee was obtained.
摘要
以含N-芳基取代恶唑烷酮的酮为催化剂、过氧化氢为主要氧化剂，对各种烯烃的不对称环氧化反应进行了研究，获得了高达96%的对映体过量值。
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